By Horst Geckeis, Thomas Rabung, Thorsten Schäfer (auth.), Stepan N. Kalmykov, Melissa A. Denecke (eds.)

This is the 1st booklet to hide actinide nano study. it truly is of curiosity either for primary study into the chemistry and physics of f-block parts in addition to for utilized researchers akin to these learning the long term defense of nuclear waste disposal and constructing remediation innovations. The authors hide vital problems with the formation of actinide nano-particles, their houses and constitution, environmental habit of colloids and nanoparticles concerning the secure disposal of nuclear wastes, modeling and complex tools of characterization on the nano-scale.

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J. Contam. , 35, 261–275. , Kim J. , and Fritz P. (1998a) Characterization of humic and fulvic acids from the Gorleben aquifer system by GPC with UV/Vis and fluorescence detection. 9th international meeting of the International Humic Substance Society. , and Kim J. I. (1998b) Effects of humic substances on the 241Am migration in a sandy aquifer: Column experiments with Gorleben groundwater/ sediment systems. Journal of Contaminant Hydrology 35, 261–275. , and Kim J. I. (2000) Characterization of groundwater humic substances: Influence of sedimentary organic carbon.

TRLFS studies on Cm(III) sorption to clay minerals at pH ! 12 shows 10 H. Geckeis et al. a Cm(III) complex 2 Cm(III) species distribution / % 100 80 Cm(III) complex 3 Cm3+ (aq) + outer-sphere surface complex 60 40 20 Cm(III) complex 1 0 4 6 8 10 12 pH b Cm(III) species distribution / % 100 Cm3+(aq) ≡ Ss / wOCm(OH)+ 80 ≡ SsOCm(OH)2 60 40 ≡ Ss / wOCm2+ 20 0 4 6 8 10 12 pH Fig. 1 Comparison of TRLFS speciation of montmorillonite bound Cm with the prediction made by using the 2SPNE/CE model [taken from Rabung et al.

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